Ask for something to be bought
A requisition is a request to buy. Once approved, your procurement team gets quotes and orders it.
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Raise a requisition
Go to My requisitions and start a new one. Say what you need and why, when it's needed by, and add a line for each item with a quantity and a rough price.
You can raise it for a colleague by choosing them under For. Select Submit for approval - the estimate helps the approver, and the buyer finds the best price.

Full size
The New requisition form with the estimate, lines and Submit for approval